Abstract

The advancement of electric vehicles demands lubricants with multifunction and performance. In this research, we investigated amphiphilic ZrP nanoparticles as lubricant additives. Experiments showed that the nanolubricant produced a tribofilm reduced the friction for 40% and wear 90%, while the electrical conductivity remained to be stable during tribotesting. Surface characterization of the tribofilm showed that there was a layered pyrophosphate on the wear track. The in situ impedance study about tribochemical kinetics revealed that the process in formation of a tribofilm involved simultaneous growth and wear. During growth, the coefficient of friction increased with continued formation of such film. During wear, the material removal rate was a function of friction, i.e., the higher the wear-rate, the higher the friction coefficient. The competing mechanisms of film growth and wear resulted in an electrically uniformed surface.

References

1.
Chen
,
Y.
,
Jha
,
S.
,
Raut
,
A.
,
Zhang
,
W.
, and
Liang
,
H.
,
2020
, “
Performance Characteristics of Lubricants in Electric and Hybrid Vehicles: A Review of Current and Future Needs
,”
Front. Mech. Eng.
,
6
.
2.
Romanenko
,
A.
,
Mütze
,
A.
, and
Ahola
,
J.
,
2015
, “
Effects of Electrostatic Discharges on Bearing Grease Electric Properties
,”
2015 IEEE International Electric Machines & Drives Conference (IEMDC)
,
Coeur d'Alene, ID
,
IEEE
, pp.
254
259
.
3.
Dai
,
W.
,
Kheireddin
,
B.
,
Gao
,
H.
, and
Liang
,
H.
,
2016
, “
Roles of Nanoparticles in Oil Lubrication
,”
Tribol. Int.
,
102
, pp.
88
98
.
4.
Chen
,
Y.
,
Renner
,
P.
, and
Liang
,
H.
,
2019
, “
Dispersion of Nanoparticles in Lubricating Oil: A Critical Review
,”
Lubricants
,
7
(
1
), p.
7
.
5.
Dai
,
W.
,
Kheireddin
,
B.
,
Gao
,
H.
,
Kan
,
Y.
,
Clearfield
,
A.
, and
Liang
,
H.
,
2016
, “
Formation of Anti-Wear Tribofilms via α-ZrP Nanoplatelet as Lubricant Additives
,”
Lubricants
,
4
(
3
), p.
28
.
6.
He
,
X.
,
Xiao
,
H.
,
Choi
,
H.
,
Díaz
,
A.
,
Mosby
,
B.
,
Clearfield
,
A.
, and
Liang
,
H.
,
2014
, “
α-Zirconium Phosphate Nanoplatelets as Lubricant Additives
,”
Colloids Surf., A
,
452
, pp.
32
38
.
7.
Xiao
,
H.
,
Dai
,
W.
,
Kan
,
Y.
,
Clearfield
,
A.
, and
Liang
,
H.
,
2015
, “
Amine-Intercalated α-Zirconium Phosphates as Lubricant Additives
,”
Appl. Surf. Sci.
,
329
, pp.
384
389
.
8.
Spikes
,
H.
,
2015
, “
Friction Modifier Additives
,”
Tribol. Lett.
,
60
(
1
), p.
5
.
9.
Spikes
,
H.
,
2004
, “
The History and Mechanisms of ZDDP
,”
Tribol. Lett.
,
17
(
3
), pp.
469
489
.
10.
Wu
,
Y. L.
, and
Dacre
,
B.
,
1997
, “
Effects of Lubricant-Additives on the Kinetics and Mechanisms of ZDDP Adsorption on Steel Surfaces
,”
Tribol. Int.
,
30
(
6
), pp.
445
453
.
11.
Fry
,
B. M.
,
Moody
,
G.
,
Spikes
,
H. A.
, and
Wong
,
J. S.
,
2020
, “
Adsorption of Organic Friction Modifier Additives
,”
Langmuir
,
36
(
5
), pp.
1147
1155
.
12.
Campen
,
S.
,
Green
,
J. H.
,
Lamb
,
G. D.
, and
Spikes
,
H. A.
,
2015
, “
In Situ Study of Model Organic Friction Modifiers Using Liquid Cell AFM; Saturated and Mono-Unsaturated Carboxylic Acids
,”
Tribol. Lett.
,
57
(
2
), p.
18
.
13.
Bancroft
,
G. M.
,
Kasrai
,
M.
,
Fuller
,
M.
,
Yin
,
Z.
,
Fyfe
,
K.
, and
Tan
,
K. H.
,
1997
, “
Mechanisms of Tribochemical Film Formation: Stability of Tribo- and Thermally-Generated ZDDP Films
,”
Tribol. Lett.
,
3
(
1
), pp.
47
51
.
14.
Sui
,
T.
,
Song
,
B.
,
Wen
,
Y.
, and
Zhang
,
F.
,
2016
, “
Bifunctional Hairy Silica Nanoparticles as High-Performance Additives for Lubricant
,”
Sci. Rep.
,
6
(
1
).
15.
Wang
,
X.
,
Zeng
,
M.
,
Yu
,
Y. H.
,
Wang
,
H.
,
Sam Mannan
,
M.
, and
Cheng
,
Z.
,
2017
, “
Thermosensitive ZrP-PNIPAM Pickering Emulsifier and the Controlled-Release Behavior
,”
ACS Appl. Mater. Inter.
,
9
(
8
), pp.
7852
7858
.
16.
Wang
,
X.
,
Zeng
,
M.
,
Yu
,
Y.-H.
,
Wang
,
H.
,
Mannan
,
M. S.
, and
Cheng
,
Z.
,
2017
, “
Thermosensitive ZrP-PNIPAM Pickering Emulsifier and the Controlled-Release Behavior
,”
ACS Appl. Mater. Interfaces
,
9
(
8
), pp.
7852
7858
.
17.
Fujita
,
H.
, and
Spikes
,
H. A.
,
2005
, “
Study of Zinc Dialkyldithiophosphate Antiwear Film Formation and Removal Processes, Part II: Kinetic Model
,”
Tribol. Trans.
,
48
(
4
), pp.
567
575
.
18.
Chen
,
Y.
,
Simon
,
B. T.
,
Opperman
,
L. A.
,
Renner
,
P.
,
Parkinson
,
D.
,
Sinyukov
,
A.
, and
Liang
,
H.
,
2021
, “
Using Nanoparticles to Prevent Enamel Wear
,”
Biotribology
,
26
, p.
100168
.
19.
Dai
,
W.
,
Chen
,
Y.
,
Lee
,
K.
,
Sinyukov
,
A. M.
,
Alkahtani
,
M.
,
Hemmer
,
P. R.
, and
Liang
,
H.
,
2017
, “
In Situ Investigation of the Growth of a Tribofilm Consisting of NaYF4 Fluorescent Nanoparticles
,”
Tribol. Trans.
, pp.
503
512
.
20.
Chen
,
Y.
, and
Liang
,
H.
,
2019
, “
Tribological Evaluation of Electrical Resistance of Lubricated Contacts
,”
ASME J. Tribol.
,
142
(
11
), p.
114502
.
21.
Chen
,
Y.
,
Wang
,
X.
,
Clearfield
,
A.
, and
Liang
,
H.
,
2019
, “
Anti-Galling Effects of α-Zirconium Phosphate Nanoparticles as Grease Additives
,”
ASME J. Tribol.
,
141
(
3
), p.
031801
.
22.
Wang
,
X.
,
Zhao
,
D.
,
Nava Medina
,
I. B.
,
Diaz
,
A.
,
Wang
,
H.
,
Clearfield
,
A.
,
Sam Mannan
,
M.
, and
Cheng
,
Z.
,
2016
, “
Surface Modification of Layered Zirconium Phosphate with PNIPAM
,”
Chem. Commun.
,
52
(
26
), pp.
4832
4835
.
23.
Chen
,
Y.
,
Renner
,
P. A.
, and
Liang
,
H.
,
2021
, “
Using Electrochemical Impendence to Characterize Thermal Performance of Working Lubricants
,”
Surf. Topogr.: Metrol. Prop.
,
9
(
3
), p.
035035
.
24.
Sun
,
L.
,
Boo
,
W. J.
,
Sue
,
H. J.
, and
Clearfield
,
A.
,
2007
, “
Preparation of α-Zirconium Phosphate Nanoplatelets with Wide Variations in Aspect Ratios
,”
New J. Chem.
,
31
(
1
), pp.
39
43
.
25.
Horsley
,
S. E.
,
Nowell
,
D. V.
, and
Stewart
,
D. T.
,
1974
, “
The Infrared and Raman Spectra of α-Zirconium Phosphate
,”
Spectrochim. Acta, Part A
,
30
(
2
), pp.
535
541
.
26.
Orendorff
,
C. J.
,
Ducey
,
M. W.
, and
Pemberton
,
J. E.
,
2002
, “
Quantitative Correlation of Raman Spectral Indicators in Determining Conformational Order in Alkyl Chains
,”
J. Phys. Chem. A
,
106
(
30
), pp.
6991
6998
.
27.
Busca
,
G.
,
Lorenzelli
,
V.
,
Galli
,
P.
,
Ginestra
,
A. L.
, and
Patrono
,
P.
,
1987
, “
A Fourier-Transform Infrared and Catalytic Study of the Evolution of the Surface Acidity of Zirconium Phosphate Following Heat Treatment
,”
J. Chem. Soc., Faraday Trans. 1
,
83
(
3
), pp.
853
864
. DOI: 10.1039/F19878300853
28.
Ali
,
A. A. M.
, and
Zaki
,
M. I.
,
2002
, “
HT-XRD, IR and Raman Characterization Studies of Metastable Phases Emerging in the Thermal Genesis Course of Monoclinic Zirconia via Amorphous Zirconium Hydroxide: Impacts of Sulfate and Phosphate Additives
,”
Thermochim. Acta
,
387
(
1
), pp.
29
38
.
29.
Mekhemer
,
G. A. H.
,
1998
, “
Characterization of Phosphated Zirconia by XRD, Raman and IR Spectroscopy
,”
Colloids Surf., A
,
141
(
2
), pp.
227
235
.
30.
Willermet
,
P. A.
,
Dailey
,
D. P.
,
Carter
,
R. O.
,
Schmitz
,
P. J.
, and
Zhu
,
W.
,
1995
, “
Mechanism of Formation of Antiwear Films From Zinc Dialkyldithiophosphates
,”
Tribol. Int.
,
28
(
3
), pp.
177
187
.
31.
Guo
,
W.
,
Zhou
,
Y.
,
Sang
,
X.
,
Leonard
,
D. N.
,
Qu
,
J.
, and
Poplawsky
,
J. D.
,
2017
, “
Atom Probe Tomography Unveils Formation Mechanisms of Wear-Protective Tribofilms by ZDDP, Ionic Liquid, and Their Combination
,”
ACS Appl. Mater. Interfaces
,
9
(
27
), pp.
23152
23163
.
32.
Costantino
,
U.
, and
La Ginestra
,
A.
,
1982
, “
On the Existence of Pyrophosphates of Tetravalent Metals Having a Layered Structure
,”
Thermochim. Acta
,
58
(
2
), pp.
179
189
.
You do not currently have access to this content.