It is environmentally friendly to use water-based emulsion instead of the oil when cold drawing Al alloy production. In this research, adopting specially prepared water-based emulsion, contact angles and tribological properties of as-selected multilayer diamond films are clarified. The contact angle on diamond film is much smaller than that on WC-Co with the same surface roughness, and tribological behaviors of the diamond film are much better. The effects of surface roughness Ra of the film, lubrication, and water content in the emulsion W are studied, indicating that the contact angle increases with W or Ra. For the diamond film, lower Ra is beneficial for reducing the coefficient of friction (COF), Al alloy ball wear and oxidation, while lower W contributes to the reduction of the COF, ball oxidation, and coated disk wear. Finally, high-speed drawing of high-quality 6021 Al alloy wires (AWs) is accomplished, proving that using coated drawing dies, the water-based emulsion (W < 80 vol %) can totally replace oil, and coated dies under the water-based emulsion lubrication present much elongated lifetime and can guarantee the production quality, compared to uncoated ones under the oil lubrication, in spite of slightly severer wire oxidation.

References

1.
Kuram
,
E.
,
Ozcelik
,
B.
,
Huseyin Cetin
,
M.
,
Demirbas
,
E.
, and
Askin
,
S.
, 2013, “
Effects of Blended Vegetable-Based Cutting Fluids With Extreme Pressure on Tool Wear and Force Components in Turning of Al 7075-T6
,”
Lubr. Sci.
,
25
(
1
), pp.
39
52
.
2.
Fratila
,
D.
, and
Caizar
,
C.
, 2011, “
Application of Taguchi Method to Selection of Optimal Lubrication and Cutting Conditions in Face Milling of AlMg3
,”
J. Cleaner Prod.
,
19
(
6–7
), pp.
640
645
.
3.
Karakulski
,
K.
, and
Morawski
,
W. A.
, 2000, “
Purification of Copper Wire Drawing Emulsion by Application of UF and RO
,”
Desalination
,
131
(
1–3
), pp.
87
95
.
4.
Su
,
Y.-Y.
, 1997, “
Enhanced Boundary Lubrication by Potential Control During Copper Wire Drawing
,”
Wear
,
210
(
1–2
), pp.
165
170
.
5.
Inspektor
,
A.
,
Oles
,
E. J.
, and
Bauer
,
C. E.
, 1997, “
Theory and Practice in Diamond Coated Metal-Cutting Tools
,”
Int. J. Refract. Met. Hard Mater.
,
15
(
1–3
), pp.
49
56
.
6.
Shen
,
B.
,
Chen
,
S.
, and
Sun
,
F.
, 2014, “
Investigation on the Long-Duration Tribological Performance of Bilayered Diamond/Diamond-like Carbon Films
,”
Proc. Inst. Mech. Eng. Part J
,
228
(
6
), pp.
628
641
.
7.
Ostrovskaya
,
L.
,
Perevertailo
,
V.
,
Ralchenko
,
V.
,
Saveliev
,
A.
, and
Zhuravlev
,
V.
, 2007, “
Wettability of Nanocrystalline Diamond Films
,”
Diamond Relat. Mater.
,
16
(
12
), pp.
2109
2113
.
8.
Hollman
,
P.
,
Wanstrand
,
O.
, and
Hogmark
,
S.
, 1998, “
Friction Properties of Smooth Nanocrystalline Diamond Coatings
,”
Diamond Relat. Mater.
,
7
(
10
), pp.
1471
1477
.
9.
Buijnsters
,
J. G.
,
Shankar
,
P.
,
Enckevort
,
W. J. P.
,
Schermer
,
J. J.
, and
Meulen
,
J. J.
, 2005, “
Adhesion Analysis of Polycrystalline Diamond Films on Molybdenum by Means of Scratch, Indentation and Sand Abrasion Testing
,”
Thin Solid Films
,
474
(
1–2
), pp.
186
196
.
10.
Dumpala
,
R.
,
Chandran
,
M.
,
Kumar
,
N.
,
Dash
,
S.
,
Ramamoorthy
,
B.
, and
Rao
,
M. S. R.
, 2013, “
Growth and Characterization of Integrated Nano- and Microcrystalline Dual Layer Composite Diamond Coatings on WC-Co Substrates
,”
Int. J. Refract. Met. Hard Mater.
,
37
, pp.
127
133
.
11.
Shen
,
B.
,
Sun
,
F.
,
Zhang
,
Z.
,
Shen
,
H.
, and
Guo
,
S.
, 2013, “
Application of Ultra-Smooth Composite Diamond Film Coated WC-Co Drawing Dies Under Water-Lubricating Conditions
,”
Trans. Nonferrous. Met. Soc.
,
23
(
1
), pp.
161
169
.
12.
Chen
,
N.
, and
Sun
,
F.
, 2013, “
Cutting Performance of Multilayer Diamond Coated Silicon Nitride Inserts in Machining Aluminum–Silicon Alloy
,”
Trans Nonferrous Met. Soc.
,
23
(
7
), pp.
1985
1992
.
13.
Wang
,
X.
,
Wang
,
L.
,
Shen
,
B.
, and
Sun
,
F.
, 2015, “
Friction and Wear Performance of Boron Doped, Undoped Microcrystalline and Fine Grained Composite Diamond Films
,”
Chin. J. Mech. Eng.
,
28
(
1
), pp.
155
163
.
14.
Chen
,
S.
,
Shen
,
B.
,
Sun
,
F.
,
Zhang
,
Z.
, and
Guo
,
S.
, 2015, “
Tribological Behaviors of Diamond Films and Their Applications in Metal Drawing Production in Water-Lubricating Condition
,”
Proc. Inst. Mech. Eng. Part J
,
230
(
6
), pp.
656
666
.
15.
Wang
,
X.
,
Wang
,
C.
, and
Sun
,
F.
, 2016, “
Development and Growth Time Optimization of the Boron-Doped Micro-Crystalline, Pristine Micro-Crystalline and Pristine Fine-Grained Composite Diamond Film
,”
Proc. Inst. Mech. Eng. Part B
,
232
(
7
), pp.
1244
1258
.
16.
Haubner
,
R.
,
Kubelka
,
S.
,
Lux
,
B.
,
Griesser
,
M.
, and
Grasserbauer
,
M.
, 1995, “
Murakami and H2SO4/H2O2 Pretreatment of WC-Co Hard Metal Substrates to Increase the Adhesion of CVD Diamond Coatings
,”
J. Phys. Arch.
,
5
, pp.
753
760
.
17.
Belmonte
,
M.
, 2005, “
Diamond Coating of Coloured Si3N4 Ceramics
,”
Diamond Relat. Mater.
,
14
(
1
), pp.
54
59
.
18.
Wang
,
X.
,
Shen
,
X.
,
Zhao
,
T.
,
Sun
,
F.
, and
Shen
,
B.
, 2016, “
Tribological Properties of MCD Films Synthesized Using Different Carbon Sources When Sliding against Stainless Steel
,”
Tribol. Lett.
,
61
(
2
), pp.
1
16
.
19.
Wang
,
X.
,
Zhang
,
T.
,
Shen
,
B.
,
Zhang
,
J.
, and
Sun
,
F.
, 2013, “
Simulation and Experimental Research on the Substrate Temperature Distribution in HFCVD Diamond Film Growth on the Inner Hole Surface
,”
Surf. Coat. Technol.
,
219
, pp.
109
118
.
20.
He
,
K.
,
Gou
,
L.
, and
Ran
,
J.
, 2018, “
Effect of Surface Component and Morphology of Diamond Film on Surface Energy
,”
J. Chin. Ceram. Soc.
,
38
(
2
), pp.
187
191
(in Chinese).
21.
Ostrovskaya
,
L.
,
Perevertailo
,
V.
,
Ralchenko
,
V.
,
Dementjev
,
A.
, and
Loginova
,
O.
, 2002, “
Wettability and Surface Energy of Oxidized and Hydrogen Plasma-Treated Diamond Films
,”
Diamond Relat. Mater.
,
11
(
3–6
), pp.
845
850
.
You do not currently have access to this content.