Abstract
Ce-doped Ba2TiMoO6 with different Ce percentage was synthesized by solid state reaction and investigated. Electrical and thermal properties were examined by using X-ray powder diffraction (XRD), scanning electron microscopy (SEM), electrochemical impedance spectroscopy (EIS), and photothermal deflection (PTD) technique. The electrical investigation shows that the increase of Ce doping percentage favors the electrical confinement which leads to a decrease in the electrical capacitance from 2.6 nF to 1.6 nF, an increase in the grain boundaries resistance from 5.88 × 107 to 6.50 × 108 Ω, a decrease in the current density from 60 nA to 3 nA, and a decrease of thermal conductivity from 1.8 W m−1 K−1 to 0.12 W m−1 K−1. These results introduce the Ce-doped Ba2TiMoO6 perovskite as a potential candidate for a new generation of thermal barrier coatings (TBCs).
Issue Section:
Research Papers
Keywords:
Ce-doped Ba2TiMoO6,
solid-state reaction,
impedance spectroscopy,
photothermal deflection (PTD) technique,
thermal conductivity,
thermal barrier coatings
Topics:
Deflection,
Electrochemical impedance spectroscopy,
Thermal conductivity,
Thermal properties,
Electrical properties,
Grain boundaries,
Scanning electron microscopy,
Thermal barrier coatings,
Temperature,
Heat,
Polarization (Electricity),
Polarization (Light),
Polarization (Waves),
Thermal diffusivity,
Density,
Fluids,
Fatigue life
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