Measurements of CO2 gasification kinetics of coal chars at temperatures of 1273–1873 K were conducted by using a bench-scale fluidized bed reactor (FBR) made of alumina. The gasification rates of chars carbonized under both rapid heating and slow heating conditions were measured using a high-volatile bituminous coal and a medium-volatile bituminous coal. The significant difference in reactivity between rapid heating chars and slow heating chars, and the decrease of char reactivity at high temperature were discussed.

1.
Kojima
,
T.
,
Furusawa
,
T.
, and
Kunii
,
D.
,
1984
, “
Measurement of Gasification Rate of Coal Char Using a Fluidized Bed
,”
Kagaku Kogaku Ronbunshu
,
11
, pp.
596
601
.
2.
Jahnke, F. C., 1997, “TEXACO Gasification for Clean Coal Utilization Controlling Ash at High Temperature and Pressure,” Proc., Advanced Clean Coal Technology International Symposium’97, Tokyo, Japan, October 2–3, pp. 111–120.
3.
Horio, M., Chen, C., Miyoshi, T., and Kamia, H., 1997, “On the Scale-up of Entrained Flow Gasifier,” Proc., Advanced Clean Coal Technology International Symposium, Tokyo, Japan, October, 2–3, pp. 133–142.
4.
Wells
,
W. F.
, and
Smoot
,
L. D.
,
1991
, “
Relation between Reactivity and Structure for Coal and Chars
,”
Fuel
,
70
, pp.
455
458
.
5.
Honma
,
S.
,
Takeda
,
S.
,
Kitano
,
K.
,
Yoshida
,
R.
,
Koyama
,
S.
, and
Ueda
,
A.
,
1998
, “
Pressurized Gasification of Entrained Coal Char from Entrained Bed Gasifier
,”
J. Jpn. Inst. Energy
,
77
, pp.
785
791
.
6.
Lee
,
J. G.
,
Kim
,
J. H.
,
Lee
,
H. J.
,
Park
,
T. J.
, and
Kim
,
S. D.
,
1996
, “
Characteristics of Entrained Flow Coal Gasification in a Drop Tube Reactor
,”
Fuel
,
75
, pp.
1035
1042
.
7.
Kojima
,
T.
,
Yamashita
,
S.
, and
Furusawa
,
T.
,
1985
, “
Effects of Devoltilization Condition on Gasification Rate of Coal Char
,”
Kagaku Kogaku Ronbunshu
,
11
, pp.
735
738
.
8.
Kojima
,
T.
,
Assavadakorn
,
P.
, and
Furusawa
,
T.
,
1993
, “
Measurement and Evaluation of gasification Kinetics of Sawdust Char with Steam in an Experimental Fluidized Bed
,”
Fuel Process. Technol.
,
36
, pp.
201
207
.
9.
Luo
,
C.
,
Aoki
,
K.
,
Uemiya
,
S.
, and
Kojima
,
T.
,
1998
, “
Numerical Simulation of a Jetting Fluidized Bed Gasifier and the Comparison to the Experimental Data
,”
Fuel Process. Technol.
,
55
, pp.
193
218
.
10.
Raghunathan
,
K.
, and
Yang
,
Y. K.
,
1989
, “
Unification of Coal Gasification Data and Its Applications
,”
Ind. Eng. Chem. Res.
,
28
, pp.
518
523
.
11.
Luo
,
C.
,
Watanabe
,
T.
,
Nakamura
,
M.
,
Uemiya
,
S.
, and
Kojima
,
T.
,
2001
, “
Development of FBR Measurements of Char Reactivity to Carbon Dioxide at Elevated Temperatures
,”
Fuel
,
80
, pp.
233
243
.
12.
Radovic
,
L. R.
,
Walker
,
P. L.
, and
Jenkins
,
J. R. G.
,
1983
, “
Importance of Carbon Active Sites in the Gasification of Coal Chars
,”
Fuel
,
62
, pp.
849
856
.
13.
Kasaoka
,
S.
,
Sakata
,
Y.
, and
Shimada
,
M.
,
1987
, “
Effects of Coal Carbonization Condition on Rate of Steam Gasification of Char
,”
Fuel
,
66
, pp.
697
701
.
14.
Senneca
,
O.
,
Russo
,
P.
,
Salatino
,
P.
, and
Masi
,
S.
,
1997
, “
The Relevance of Thermal Annealing to the Evolution of Coal Char Gasification Reactivity
,”
Carbon
,
35
, pp.
141
151
.
15.
Kajitani, S., and Matsuda, H., 1982, “Influence of Pyrolysis Conditions on Coal Gasification Reactivity,” Yokosuka Research Laboratory Report No. W97020, Japan.
16.
Smith, I. W., 1982, “The Combustion Rates of Coal Chars: A Review,” 19th Int. Symp. Combustion, The Combustion Institute, Pittsburgh, PA, pp. 1045–1065.
17.
Smith, K. L., Smoot, L. D., Fletcher T. H., and Pugmire, R. J., 1994, The Structure and Reaction Processes of Coal, Plenum Press, New York, NY, and London, UK.
You do not currently have access to this content.