In this paper we analyze the three-dimensional flow field in anode and cathode gas channels of polymer electrolyte membrane (PEM) fuel cells operating at high temperature (T >100 °C). Different gas flow channel designs (pin-type, parallel channels, comb-tipe and multiple serpentine), as well as different channel sections (squared, trapezoidal and rounded with different curvature radii) are evaluated in function of some relevant parameters. The analysis is performed accounting for overall pressure losses, gas distribution over the electrode area and residence time with focus on channel hydraulic diameter, active surface ratio, gas path. Differences with low temperature (LT) PEM fuel cell design are also adressed. The investigation is conducted by means of 3D-CFD softwares and the results of our simulations are compared to experimental data in literature.
Issue Section:
Research Papers
References
1.
Zhang
, J.
, Xie
, Z.
, Zhang
, J.
, Tang
, Y.
, Song
, C.
, Navessin
, T.
, Shi
, Z.
, Song
, D.
, Wang
, H.
, Wilkinson
, D. P.
, Liu
, Z.-S.
, and S. Holdcroft
, S.
, 2006, “High Temperature PEM Fuel Cells
,” J. Power Sources
160
, pp. 872
–891
.2.
Cozzolino
, R.
, Cicconardi
, S. P.
, Galloni
, E.
, Minutillo
, M.
, and Perna
, A.
, 2011, “Theoretical and Experimental Investigations on Thermal Management of a PEMFC Stack
,” Int. J. Hydrogen Energy
36
, pp. 8030
–8037
.3.
P.T. Nguyen
, P. T.
, 2003, “A Three-Dimensional Computational Model of PEM Fuel Cell with Serpentine Gas Channels
,” Master’s thesis, University of Victoria, Canada.4.
Zhang
, J.
, Tang
, Y.
, Song
, C.
, Cheng
, X.
, Zhang
, J.
, and Wang
, H.
, 2007, “PEM Fuel Cells Operated at 0% Relative Humidity in the Temperature Range of 23° –120 °C.
Electrochim. Acta
, 52
(15
), pp. 5095
–5101
.5.
Bhatia
, K. K.
, and Wang
, C.-Y.
, 2004, “Transient Carbon Monoxide Poisoning of a Polymer Electrolyte Fuel Cell Operating on Diluted Hydrogen Feed
,” Electrochim. Acta
49
, pp. 2333
–2341
.6.
Baschuk
, J. J.
, and Li
, X.
, 2003, “Modelling CO Poisoning and O2 Bleeding in a PEM Fuel Cell Anode
,” Int. J. Energy Res.
, 27
, 1095
–1116
.7.
de Bruijn
, F. A.
, Papageorgopoulos
, E. F.
, anf Sitters
, D. C.
, and Janssen
, G. J. M.
, 2002, “The Influence of Carbon Dioxide on Pem Fuel Cell Anodes
,” J. Power Sources
, 110
, pp. 117
–124
.8.
Brett
, D. J. L.
, Aguiar
, P.
, Brandon
, N. P.
, and Kucernak
, A. R.
, 2007. “Measurement and Modelling of Carbon Monoxide Poisoning Distribution Within a Polymer Electrolyte Fuel Cell
, Int. J. Hydrogen Energy
, 32
, pp. 863
–871
.9.
Minutillo
, M.
, and Perna
, A.
, 2008, “Behaviour Modelling of a PEMFC Operating on Diluted Hydrogen Feed
, Int. J. Energy Res.
, 32
, pp. 1297
–1308
.10.
Jannelli
, E.
, Minutillo
, M.
, and Galloni
, E.
, 2007, “Performance of a Polymer Electrolyte Membrane Fuel Cell System Fueled with Hydrogen Generated by a Fuel Processor
,” ASME J. Fuel Cell Sci. Technol.
, 4
, pp. 435
–440
.11.
Cicconardi
, S. P.
, Jannelli
, E.
, Perna
, A.
, and Spazzafumo
, G.
, 1999, “A Steam Cycle with an Isothermal Expansion: The Effect of Flow Variation
,” Int. J. Hydrogen Energy
, 24
, pp. 53
–57
.12.
Cicconardi
, S. P.
, Jannelli
, E.
, Perna
, A.
, and Spazzafumo
, G.
, 2001, “Parametric Analysis of a Steam Cycle with a Quasi-Isothermal Expansion
,” Int. J. Hydrogen Energy
, 26
, pp. 275
–279
.13.
Peng
, J.
, and Lee
, S. J.
, 2006, “Numerical Simulation of Proton Exchange Membrane Fuel Cells at High Operating Temperature
,” J. Power Sources
162
, p. 118291
.14.
Lobato
, J.
, Cañizares
, P.
, Rodrigo
, M. A.
, Linares
, J. J.
, and Aguila
, J. A.
, 2007, “Improved Polybenzimidazole Films for H3PO4-doped PBI-based High Temperature PEMFC
,” J. Membr. Sci.
306
, pp. 47
–55
.15.
Li
, X.
, and Sabir
, I.
, 2006, “Review of Bipolar Plates in PEM Fuel Cells: Flow-Field Designs
,” Int. J. Hydrogen Energy
, 30
, pp. 359
–371
.16.
Li
, X.
, Sabir
, I.
, and Park
, J.
, 2007, “A Flow Channel Design Procedure for Pem Fuel Cells with Effective Water Removal
,” J. Power Sources
163
(2
), pp. 933
–942
.17.
Ansys, 2005, Fluent 6.3 User’s Guide, Canonsburg, PA.
18.
Lobato
, J.
, Cañizares
, P.
, Rodrigo
, M. A.
, Pinar
, F. J.
, Mena
, E.
, and Ú beda
, D.
, 2010, “Three-Dimensional Model of a 50 cm2High Temperature PEM Fuel Cell Study of the Flow Channel Geometry Influence
,” Int. J. Hydrogen Energy
, 35
, pp. 5510
–5520
.19.
Taccani
, R.
, and Zuliani
, N.
, 2010, “Effect of Flow Field Design on Performances of High Temperature Pem Fuel Cells: Experimental Analysis
,” Int. J. Hydrogen Energy
, 36
, pp. 10282
–10287
.20.
Erni
, M.
, Wan Ramli
, W. D.
, and Edy Herianto
, M.
, 2010, “Review on Serpentine Flow Field Design for PEM Fuel Cell Systems
, ” Key Eng Mat.
, 447–448
, pp. 559
–563
.21.
Silvestroni
, P.
, Fondamenti di Chimica
, 1996, CEA - Zanichelli
, Bologna, Italy
.23.
Berning
, T.
, and Djilaliz
, N.
, 2003, “A 3D, Multiphase, Multicomponent Model of the Cathode and Anode of a PEM Fuel Cell
, J. Electrochem. Soc.
, 150
(12
), pp. A1589
–A1598
.24.
Robalinho
, E.
, Cunha
, E. F.
, Andrade
, A. B.
, Bejarano
, M. L. M.
, Linardi
, M.
, and Cekinski
, E.
, 2007, “Comsol Modelling and Simulation of PEM Fuel Cells Flow Channels,” Excerpt from the Proceedings of the COMSOL Conference.25.
Natarajan
, D.
, and Van Nguyen
, T.
, 2003, “Three-Dimensional Effects of Liquid Water Flooding in the Cathode of a PEM Fuel Cell
,” J. Power Sources
, 115
(1
), pp. 66
–80
.26.
Weber
, A. Z.
, Darling
, R. M.
, and Newman
, J.
, 2004, “Modeling Two-Phase Behavior in PEMFCs
,” J. Electrochem. Soc.
, 151
(10
), p. A1715
.27.
Chibbaro
, S.
, Falcucci
, G.
, Chiatti
, G.
, Chen
, H.
, Shan
, X.
, and Succi
, S.
, 2008, “Lattice Boltzmann Models for Nonideal Fluids with Arrested Phase-Separation
,” Phys. Rev. E
, 77
, p. 036705
.28.
Falcucci
, G.
, Ubertini
, S.
, and Succi
, S.
, 2010, “Lattice Boltzmann Simulations of Phase-Separating Flows at Large Density Ratios: The Case of Doubly-Attractive Pseudo-Potentials
,” Soft Matter
, 6
, pp. 4357
–4365
.29.
Anderson
, R.
, Zhang
, L.
, Ding
, Y.
, Blanco
, M.
, Bi
, X.
, and Wilkinson
, D. P.
, 2010, “A Critical Review of Two-Phase Flow in Gas Flow Channels of Proton Exchange Membrane Fuel Cells
, J. Power Sources
, 195
, pp. 4531
–4553
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